Fundamentals of Chemistry

  • 6 years ago
Chemistry is the science that studies the composition and structure of matter and the changes it undergoes. Because everything in the universe is composed of matter, chemistry is the study of our material world. The chemical touches our lives and influences our activities in many ways that are often called the nuclear science. We chemistry practice all the time in our daily activities, i.e., the act of cooking, washing, taking medicine, fertilize the lawn, paint the house, or light a match, for example, are directly related to this science. In all these activities, substances interact and chemical changes occur. In our body when we breathe, walk and suffer food digestion, chemical reactions occur regularly. The environmental problems we experience and we deal today, as the disposal of domestic and industrial wastewater, acid rain, the greenhouse effect, photochemical smog, among many others, are all primarily chemical problems. Many goods are now made of polymers and ceramics instead of wood and metal thanks to our ability to produce materials with properties not found in nature. However, chemistry is essential in the current revolution in molecular biology, which is exploring the details of how life is genetically controlled, that is, no one today can understand the modern world without a basic knowledge of chemistry.
Transcript
00:08Why to study chemistry?
00:11Chemistry is the science
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined4
undefined:undefined
undefined:undefinedstudy of our material world.
00:25The chemical touches our lives
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undefined:undefined
undefined:undefinedwashing, taking medicine,
00:41fertilize the lawn, paint the
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undefined:undefined
undefined:undefinedwalk and suffer food
00:57digestion, chemical
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undefined:undefined
undefined:undefinedphotochemical smog, among
01:13many others, are all
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undefined:undefined
undefined:undefinedthe current revolution in molecular
01:31biology, which is exploring the details
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undefined:undefined
undefined:undefined
undefined:undefined
undefined:undefinedreal word, from the Latin.
01:56In Latin, it means matter "what
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undefined:undefined30
undefined:undefined
undefined:undefinedto study how matter is organized.
02:12The first manifestation
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undefined:undefined
undefined:undefined(now southeastern Turkey).
02:26It is impossible to have the
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undefined:undefined
undefined:undefinedfrom its very beginning, this
02:40new way of thinking contained
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undefined:undefined
undefined:undefinedsubsequent scientific thought.
02:56Tales asked the questions:
02:58"Why do things happen as they do?"
03:00And "What the world is
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undefined:undefined48
undefined:undefined
undefined:undefinedunderlying unity to the world's diversity.
03:16But perhaps the most
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undefined:undefined
undefined:undefinedcontemplate and speculate" - testable.
03:31We know today that all
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undefined:undefined
undefined:undefinedthe atom can not be directly
03:46visualized, and then imagined
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undefined:undefined
undefined:undefinedaccepted as satisfactorily
04:00explain the phenomena
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undefined:undefined
undefined:undefinedone possibility envisioned
04:14by the human mind, always
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undefined:undefined
undefined:undefinedcomposed of tiny bits of
04:31matter has come up with
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undefined:undefined
undefined:undefinedform, position, and arrangement.
04:49All matter is made of indivisible
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undefined:undefined
undefined:undefinedDalton established changes
05:07in the atomic theory, which
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undefined:undefined80
undefined:undefined
undefined:undefinedof Democritus, although correct,
05:24was philosophical as it did not
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undefined:undefined
undefined:undefinedwhich are called atoms.
05:412 ** - All atoms of the same
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undefined:undefined88
undefined:undefined
undefined:undefinedformed when atoms combine
05:58in a constant and
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undefined:undefined
undefined:undefinedlater, changes the second assumption
06:17since isotopes are atoms of the same
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undefined:undefined
undefined:undefinedof one of the symbologies.
06:34The use of abstract symbols ended
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undefined:undefined
undefined:undefinedtime to change things he changed.
06:58Given that the old symbols were
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undefined:undefinedname of each elementary substance.
07:14The electron discovery
07:16In the nineteenth century, the works
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undefined:undefined
undefined:undefinedso-called cathode ray tube, i.e. a glass
07:39bulb connected to a vacuum pump, which
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undefined:undefinedabout one-tenth of ambient pressure,
07:54it is observed that the gas between
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undefined:undefined
undefined:undefineddisappears, leaving
08:07only a light spot behind
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undefined:undefined
undefined:undefined
undefined:undefinedthe atomic model of Thomson, who
08:23has used the electron to update
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undefined:undefined126
:undefined
undefined:undefinedbe distributed in the atom?".
08:37Thomson suggested that the total
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undefined:undefined130
undefined:undefined
undefined:undefinedcompact, uniform mass.
08:51In this mass surface would be
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undefined:undefined
undefined:undefineddivisibility of the atom, but the atom
09:11was regarded as a positively charged
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undefined:undefinedexperience, which will be described below.
09:30The atom of Rutherford
09:33The second and third major innovation came
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undefined:undefined143
undefined:undefined
undefined:undefinedand subsequently a dynamic model.
09:52To develop its atomic model
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undefined:undefined
undefined:undefinedelement) on a thin golden plate,
10:08to see whether these
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undefined:undefined
undefined:undefinedthe atoms were massive,
10:20using, for this, α particles, which have a
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undefined:undefined
undefined:undefinedbe gold, may be another metal.
10:39However, gold has been
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:undefined
undefined:undefinedcan pass through the
10:51gold plate without
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undefined:undefined
undefined:undefinedpass through the blade, but
11:04suffering an unyielding
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undefined:undefined
undefined:undefinednot penetrate the leaf and
11:19return to the same side from
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undefined:undefined
undefined:undefinedpreviously proposed by Thomson as a compact
11:34mass of positive charges distributed
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undefined:undefined175
undefined:undefined176
undefined:undefined
undefined:undefinedthe atom is in a small central
11:54region (the core) having positive
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undefined:undefined
undefined:undefinedaround the nucleus (in the electron).
12:15Although sophisticated and accessible,
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undefined:undefinedof Rutherford, electrons
12:30could orbit the nucleus
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undefined:undefined
undefined:undefined(which deals with
12:41the movement of electrons)
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undefined:undefined
undefined:undefinedtend to spiral into the nucleus.
12:56It means that atoms would be unstable,
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undefined:undefined
undefined:undefinedof these comments
13:11were regarding the behavior
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undefined:undefined
undefined:undefinedthe radiation emitted by solid
13:23which is spread evenly across
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undefined:undefined
undefined:undefinedbe at any distance from the nucleus,
13:38but confined to discrete the same
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undefined:undefined209
undefined:undefined
undefined:undefinedthis mathematical model and the succeeding,
14:02the full sophisticated
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undefined:undefined
undefined:undefinedof people who understand.
14:16The atomic theory of Bohr was
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undefined:undefined
undefined:undefinedof Rutherford with three postulates.
14:321- The electrons revolve around
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undefined:undefined
undefined:undefinedenergy to an orbital of lower energy.
14:53ΔE = h.f, the energy emitted
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undefined:undefined225
undefined:undefined
undefined:undefinedinteger multiple of h / 2π.
15:10Thus, the third postulate tells us
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undefined:undefined229
undefined:undefined
undefined:undefinedwill be presented later)
15:28n = 1,2,3,4,5,6, .... ∞
15:37In the atomic model of Bohr, we note that:
15:411. The atomic model of Bohr explains
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined235
undefined:undefined
undefined:undefinedonly one electron).
15:573. Does not explain the narrow spectrum.
16:014. Calculations rays and
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undefined:undefined240
undefined:undefined
undefined:undefinedpulses, packets, or quanta.
16:237. Ray discontinuous in heels or wrists.
16:28Application of the Bohr model
16:31• Flame test;
16:32• Fireworks;
16:34• Bright and lamps (neon
undefined:undefined00:00:15,019 --> 00:00:18,181
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undefined:undefined
undefined:undefinedif the orbits were circular.
17:04Then Sommerfeld suggested that the
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined256
undefined:undefined
undefined:undefinedthe azimuthal quantum
17:20number, which defines the
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undefined:undefined260
undefined:undefined
undefined:undefined0 and elliptical).
17:39For any principal quantum number n,
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undefined:undefined
undefined:undefinedfrom other scientists, namely:
17:57• Louis Victor de Broglie (1925):
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undefined:undefined
undefined:undefinedscientists Davisson and Germer.
18:16• Werner Heisenberg (1927):
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undefined:undefined
undefined:undefinedpossible to establish defined orbits.
18:34This statement received
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undefined:undefined
undefined:undefinedthat allow determining the energy and
18:50regions of the probability of finding the
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undefined:undefined
undefined:undefinedmodel of the Rutherford-Bohr atom
19:08and appeared a new atomic model, the
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undefined:undefined
undefined:undefinedvarious features atoms.
19:31In an electrically
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undefined:undefined290
undefined:undefined
undefined:undefined
undefined:undefined
undefined:undefinedto 26 mass number (A): The sum
19:57of the number of protons and
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undefined:undefined297
undefined:undefined
undefined:undefinedthe difference between
20:20the mass number (A) and
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undefined:undefined
undefined:undefinedthan negative charges (electrons).
20:43It occurs because the atom lost electrons.
20:46The total number of
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undefined:undefined307
undefined:undefined308
undefined:undefined
undefined:undefinedatom electrons gained.
21:12The total gains electrons are equal to
undefined:undefined00:00:15,019 --> 00:00:18,181
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undefined:undefined
undefined:undefinednegative, determines the valence.
21:37The cations and anions can be
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undefined:undefined317
undefined:undefined
undefined:undefinedatomic mass medium or medium
22:01atomic weight) is the average
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undefined:undefined321
undefined:undefined
undefined:undefinedto represent as amu).
22:17• Molecular weight: it
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined325
undefined:undefined
(1.0 x 2) + :undefined(16 x 1) = 18u
22:34• Mol: is the unit of measurement
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undefined:undefined329
undefined:undefined
undefined:undefinedhas 6,023 x 1023 molecules of this gas.
23:00One mole atoms of any element weigh
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undefined:undefined333
undefined:undefined
Molar mass is the mass :undefinedof moles of atoms of any element.
23:26The molar mass of an element
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undefined:undefined337
undefined:undefined
numerical constant :undefinedapplied both in chemistry and in physics.
23:44The formal definition of the Avogadro
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined341
undefined:undefined
Why always Carbon-12? :undefined
undefined:undefinedchosen as a reference substance
24:12because its atomic mass can
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undefined:undefined346
undefined:undefined
undefined:undefinedpressure and temperature.
24:29CNTP5 in the molar volume equals 22.71
undefined:undefined00:00:15,019 --> 00:00:18,181
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undefined:undefined351
undefined:undefined
undefined:undefinedbut have different mass numbers (A).
24:59• Isobars are atoms
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undefined:undefined
undefined:undefineddifferent atomic and mass
25:13numbers, but with the
undefined:undefined00:00:15,019 --> 00:00:18,181
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undefined:undefined360
undefined:undefined
undefined:undefinedquantity is a number which
25:32expresses a quantity compared
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undefined:undefined364
undefined:undefined
undefined:undefinedpreviously known, a standard mass.
25:50For this determination, it
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined368
undefined:undefined
undefined:undefinedof a portion expressed
26:05matter how much space
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined372
undefined:undefined
undefined:undefined
undefined:undefineddecimeter (dm³) per liter (L), cubic
26:26centimeter (cc), milliliter
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undefined:undefined377
undefined:undefined
undefined:undefinedused in the chemical liter (L).
26:45General Properties of Matter
26:49Are the properties of
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined382
undefined:undefined
undefined:undefinedthe extension of a body.
27:03Your body, for example, has the
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined386
undefined:undefined
undefined:undefineda body, the harder it
27:18is to change its movement
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undefined:undefined390
undefined:undefined
the :undefinedproperty of matter that is to
27:36have low volume when subjected
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undefined:undefined394
undefined:undefined
property :undefinedthat the matter has
27:51to be divided into smaller
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undefined:undefined398
undefined:undefined399
undefined:undefined
When burned:undefinedinto gasses, smoke, and ash.
28:13Specific properties of matter
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undefined:undefined403
undefined:undefined
undefined:undefined
the ability :undefinedof a substance to reflect
28:31light is what determines
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined409
undefined:undefined410
undefined:undefined
undefined:undefined
:undefinedperceived by touch;
28:59• Hardness: Resistance is
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined415
undefined:undefined
undefined:undefinedanother leaving a groove.
29:12To determine the hardness of
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined419
undefined:undefined
undefined:undefinedmaterials such as glass.
29:30• Malleability: property that
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined423
undefined:undefined
copper:undefined
found through :undefinedreason (division) between
29:55the mass of a substance and
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined428
undefined:undefined
undefined:undefinedpieces of lead, all sink.
30:08Some people try to explain this by
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined432
undefined:undefined
undefined:undefinedmatter the dough: pieces of
30:25cork floating in the water
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined436
undefined:undefined437
undefined:undefined
undefined:undefineddividing its mass by its volume.
30:43State of matter
30:45All matter is made up of small particles
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undefined:undefined442
undefined:undefined
:undefinedsolid, liquid and gaseous.
31:02The stones, ice, and wood are
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined446
undefined:undefined
undefined:undefinedof aggregation has its
31:20characteristics - such
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined450
undefined:undefined
undefined:undefinedstate, undergoes changes
31:33in its macroscopic
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined454
undefined:undefined
undefined:undefined
undefined:undefinedcomes from the Latin corpu.
31:49A body is a limited portion of matter.
31:52For example, the noun designates
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined460
undefined:undefined461
undefined:undefined
undefined:undefinedphysical space or not
32:09containing matter and that
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined465
undefined:undefined
undefined:undefined
undefined:undefinedis the rest of the universe.
32:26Molecules
32:28From Latin molecule, it
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined471
undefined:undefined
undefined:undefinedor a chemical compound
32:41that can exist in the free
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined475
undefined:undefined
undefined:undefinedbut gaseous hydrogen and gaseous oxygen.
33:01Types of transformations
33:03By analyzing the changes
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined480
undefined:undefined
undefined:undefinedas folding and unfolding a sheet of paper.
33:20The other type of transformation occurs
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined484
undefined:undefined
undefined:undefinedor both receive the phenomenon name.
33:38The phenomena can be divided into Chemical
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined488
undefined:undefined
undefined:undefinedDollar is a chemical phenomenon.
33:56• Physical hazards are those
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined492
undefined:undefined
undefined:undefineda physical phenomenon.
34:10Chemical elements
34:12Everything that is
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined497
undefined:undefined
undefined:undefinedi.e. are pure substances existing in nature.
34:29Silver, mercury and sulfur
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined501
undefined:undefined
undefined:undefinedparticle accelerators.
34:47Each chemical element is represented
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined505
undefined:undefined
undefined:undefinedthat is found in nature,
35:01some characteristic of the
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined509
undefined:undefined
undefined:undefined
undefined:undefinedspectrum analysis of
35:20sunlight, is the sun god
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined514
undefined:undefined
undefined:undefinedtheir representation.
35:35The nomenclature most widely accepted
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined518
undefined:undefined
undefined:undefined
undefined:undefinedthey form thousands of different chemicals!
36:00How is this possible?
36:02Only because the atoms of chemical
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined524
undefined:undefined
undefined:undefinedchapter chemical bonds).
36:18Each group forms a chemical.
36:21The graphical representation of the chemical
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined529
undefined:undefined
undefined:undefinedformula of water is H₂O.
36:39So when we say that the
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined533
undefined:undefined
undefined:undefinedatom of element oxygen.
36:52The most widely used
undefined:undefined00:00:15,019 --> 00:00:18,181
undefined:undefined537
undefined:undefined
undefined:undefinedare interconnected.
37:03The other types are the gross
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undefined:undefined

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